THE PYROLYSIS OF TETRAFLUOROHYDRAZINE.
GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY
Pagination or Media Count:
The pyrolysis of tetrafluorohydrazine was studied in a passivated monel bulb over the temperature range 315-520C and at pressures from about 30-700 torr. The stoichiometry was confirmed by gas chromatographic analysis, and the reaction kinetics investigated manometrically and analytically. 6NF2 yields 4NF3 N2. The reaction rate was found to exhibit good second order behavior at temperatures above 405C. Evidence is presented that the reaction is homogeneous and the mechanism is bimolecular. Author
- Inorganic Chemistry
- Physical Chemistry