Accession Number:

AD0707436

Title:

1-SILYL DERIVATIVES OF PENTABORANE (9).

Descriptive Note:

Technical rept.,

Corporate Author:

WISCONSIN UNIV MADISON DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1970-06-01

Pagination or Media Count:

10.0

Abstract:

It was found that gas phase thermolysis of mu-CH33SiB5H8 at about 80C results in irreversible formation of 2-CH33SiB5H8 at a reasonable rate. At higher temperatures further isomerization occurs to produce 1-CH33SiB5H8. This isomerization, however, is reversible and 1-CH33SiB5H8 predominates by a factor of about 3.3 at 120C. Gas phase thermolysis of 2-H3SiB5H8 at 150C results in a similar conversion to 1-H3SiB5H8. This isomerization also appears to be reversible. Author

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE