Accession Number:
AD0707428
Title:
THE PYROLYSIS OF DIFLUORAMINE.
Descriptive Note:
Technical rept.,
Corporate Author:
GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY
Personal Author(s):
Report Date:
1970-06-01
Pagination or Media Count:
28.0
Abstract:
The pyrolysis of difluoramine has been investigated over the temperature range 275-351C. Evidence is presented that in Teflon and Monel vessels the reaction is heterogeneous while in Pyrex Bulbs it is not. The reaction in the Pyrex bulb corresponded to a stoichiometry of 4HNF2 to 4HF N2 N2F4. The reaction kinetics could only be interpreted in terms of inhibition by a product. The kinetics were analyzed and an activation energy of about 43 kcal.mole was deduced. Possible reaction mechanisms are discussed. Author
Descriptors:
Subject Categories:
- Physical Chemistry