THE PYROLYSIS OF DIFLUORAMINE.
GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY
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The pyrolysis of difluoramine has been investigated over the temperature range 275-351C. Evidence is presented that in Teflon and Monel vessels the reaction is heterogeneous while in Pyrex Bulbs it is not. The reaction in the Pyrex bulb corresponded to a stoichiometry of 4HNF2 to 4HF N2 N2F4. The reaction kinetics could only be interpreted in terms of inhibition by a product. The kinetics were analyzed and an activation energy of about 43 kcal.mole was deduced. Possible reaction mechanisms are discussed. Author
- Physical Chemistry