Accession Number:

AD0707428

Title:

THE PYROLYSIS OF DIFLUORAMINE.

Descriptive Note:

Technical rept.,

Corporate Author:

GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1970-06-01

Pagination or Media Count:

28.0

Abstract:

The pyrolysis of difluoramine has been investigated over the temperature range 275-351C. Evidence is presented that in Teflon and Monel vessels the reaction is heterogeneous while in Pyrex Bulbs it is not. The reaction in the Pyrex bulb corresponded to a stoichiometry of 4HNF2 to 4HF N2 N2F4. The reaction kinetics could only be interpreted in terms of inhibition by a product. The kinetics were analyzed and an activation energy of about 43 kcal.mole was deduced. Possible reaction mechanisms are discussed. Author

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE