Accession Number:

AD0706187

Title:

MODIFICATION OF POLYACRYLONITRILE FIBER BY GRAFT COPOLYMERIZATION,

Descriptive Note:

Corporate Author:

FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Report Date:

1970-01-30

Pagination or Media Count:

12.0

Abstract:

The acrylonitrile 4-beta-vinylsulfonyl-2-aminoanisole copolymer I PANV fiber was modified by graft copolymn. with Me acrylate II, Bu acrylate III, or acrylic acid IV in the presence of a redox system composed of HVO3 plus H2SO4. The graft copolymerization kinetics was markedly affected by fiber orientation. Smaller degree of drawing and higher reaction temp. brought about increased polymn. rate. The grafted copolymers-exhibited higher loop strength, wear resistance, and in the case of I-IV graft copolymer, also increased flexural strength.

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE