EMPIRICAL CORRELATIONS OF MOLECULAR CONSTANTS FOR CARBON-CARBON, CARBON-NITROGEN, CARBON-OXYGEN, NITROGEN-NITROGEN, NITROGEN-OXYGEN AND OXYGEN-OXYGEN BONDS,
MELBOURNE UNIV PARKVILLE (AUSTRALIA) DEPT OF CHEMISTRY
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The molecular constants considered in this paper are the bond length l, the bond order and overlap population P, the quadratic stretch-stretch force constant f, and the bond dissociation energy D. Briefly reviewed are the different types of l, P, f and D values in present use, chosen a consistent set of equations for their correlation and evaluated the empirical constants present in these equations, from a set of standard molecules for each bond-type, for which accurate experimental values of l, P, f and D were available.
- Atomic and Molecular Physics and Spectroscopy