Accession Number:

AD0705535

Title:

RAMAN SCATTERING FROM THE HYDROXYL ION IN ALKALI HALIDES.

Descriptive Note:

Doctoral thesis,

Corporate Author:

ILLINOIS UNIV URBANA

Personal Author(s):

Report Date:

1969-07-01

Pagination or Media Count:

78.0

Abstract:

Raman scattering has been observed from the hydroxyl ion in NaCl, Kcl, and KBr crystals. The measurements were made using an argon ion laser as a light source and a tandem double monochromator with photoelectric detection. A Raman emission attributed to the stretching motion of the OH9- ion was seen in all samples. The stretching bands in KBrOH- and KClOH- showed no resolvable structure. However, at 15 K, the stretching band in NaClOH- appeared to be composed of two lines separated by about 2.8cm. RRaman scattering from the stretching level of OD- doped NaCl was observed whereas no corresponding infrared absorption has been seen. Author

Subject Categories:

  • Atomic and Molecular Physics and Spectroscopy
  • Solid State Physics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE