Accession Number:

AD0701702

Title:

SALTING EFFECTS IN SEVERAL ALCOHOL-ELECTROLYTE-WATER SYSTEMS,

Descriptive Note:

Corporate Author:

KENTUCKY UNIV LEXINGTON DEPT OF CHEMISTRY

Personal Author(s):

• Campbell,Harold R.
• Shallal,Abdul K.
• Bauer,Henry H.

Report Date:

1969-12-01

Pagination or Media Count:

8.0

Abstract:

Salting effects of sodium sulfate, potassium fluoride, potassium chloride, sodium perchlorate, and perchloric acid on cyclohexanol, 1-pentanol, and 1-butanol were determined by measuring the solubilities of the alcohols in the various electrolyte solutions. Solubilities were determined by color development and spectrophotometry. The relevant Setschenow parameters are reported. There was no apparent correlation between the salting effect and the dipole moment of the alcohol. These data can be used to interpret results of studies of the adsorption of the alcohols at electrode surfaces in the presence of these salts. Author

Descriptors:

• (*ALCOHOLS
• SOLUBILITY)
• (*ELECTROLYTES
• ALCOHOLS)
• SALTS
• CYCLOHEXANOLS
• PENTANOLS
• BUTANOLS

Subject Categories:

• Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE