Accession Number:

AD0701120

Title:

INFRARED STUDIES USING THE MATRIX ISOLATION TECHNIQUE.

Descriptive Note:

Final rept. 15 Jun 67-30 Sep 69,

Corporate Author:

TEXAS TECH UNIV LUBBOCK DEPT OF CHEMISTRY

Personal Author(s):

• Redington,Richard L.

Report Date:

1969-09-30

Pagination or Media Count:

89.0

Abstract:

Briefly summarized are the results of research using matrix isolation techniques to study the infrared spectra of reactive halogen compounds such as SbF5, AsF5, ClF3, BrF3, BrF5, LiF, CH3COOH, and CCl3COOH. The main text of the report consists of four articles with the following titles Infrared matrix-isolation spectra and the mechanism for F atom exchange in ClF3, BrF3, and SF4 On the calculation of unique force constants F2O, O3, Cl2O, H2S, H2O, NF3, H2CO Properties of LiF molecules and Infrared spectra of matrix isolated acetic acid monomers.

Descriptors:

• (*INFRARED SPECTRA
• *HALIDES)
• (*FLUORIDES
• INFRARED SPECTRA)
• (*LITHIUM FLUORIDES
• INFRARED SPECTRA)
• (*ACETIC ACID
• INFRARED SPECTRA)
• OZONE
• VIBRATION
• MOLECULAR ENERGY LEVELS
• NITROGEN COMPOUNDS
• CHLORINE COMPOUNDS
• BROMINE COMPOUNDS
• SULFUR COMPOUNDS
• DEUTERIUM COMPOUNDS

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry
• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE