Accession Number:

AD0699011

Title:

THE OXIDATION OF AMINES WITH PEROXY RADICALS. N-PHENYL-2-NAPTHYLAMINE,

Descriptive Note:

Corporate Author:

NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF APPLIED CHEMISTRY

Report Date:

1969-05-09

Pagination or Media Count:

7.0

Abstract:

Six products have been identified in the oxidation of N-phenyl-2-naphthylamine by peroxy radicals. Three of the products, 1.1-bisN-phenyl-2-naphthylamine, N,N-diphenyl-N-2-naphthyl-1,2-naphthylenediamine, and 7-phenyl-dibenzoc,gcarbazole, are formed by the coupling of amino radicals. The remaining products, 2-anilino-1,4-naphthoquinone, 2-anilino-1,4-naphthoquinone-4-anil, and 4-N-phenyl-2-naphthylamino-1,2-naphthoquinone, are believed to be formed by the attack of various nucleophiles on 1,2-naphthoquinone-2-anil. This o-quinone imine was not identified among the products, but it is probably formed in the reaction of amino radicals with peroxy radicals. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE