Accession Number:

AD0698074

Title:

VOLATILE FLUORO- AND TRIFLUORO-METHYL DIPHOSPHORUS COMPOUNDS CONTAINING PHOSPHORUS IN TWO VALENCIES,

Descriptive Note:

Corporate Author:

ALBERTA UNIV EDMONTON DEPT OF CHEMISTRY

Report Date:

1969-02-18

Pagination or Media Count:

1.0

Abstract:

Reported attempts to prepare quinquevalent diphosphorus compounds from bistrifluoromethyliodophosphine sulphide, CF32PSI and iodothiophosphoryl difluoride, SPF2I, were unsuccessful. It was found that the reaction of the above iodophosphorus compounds with stoicheiometric quantities of metallic mercury at room temperature gives the desired diphosphorus disulphide compounds 2X2PSI Hg yields X4P2S2 HgI2X F,CF3. The reactions are slow and require vigorous agitation to renew the reactive metal surface. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE