HIGH TEMPERATURE REACTIONS OF SUBSTITUTED PYRROLES.
Final rept. 1 Sep 65-30 Sep 69,
KENTUCKY RESEARCH FOUNDATION LEXINGTON
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Research was undertaken to elucidate product formation and the reaction path followed in the thermally-induced isomerization of N-substituted pyrroles. Various parameters such as the effect of substituents pyrrole-ring substituents and migrating-group substituents on migration aptitudes, on product distribution and on reaction rate were investigated. The study of a reaction in which the potential migrating group is optically active was proposed in order to determine the nature of migration process. Author
- Organic Chemistry