Accession Number:

AD0698043

Title:

HIGH TEMPERATURE REACTIONS OF SUBSTITUTED PYRROLES.

Descriptive Note:

Final rept. 1 Sep 65-30 Sep 69,

Corporate Author:

KENTUCKY RESEARCH FOUNDATION LEXINGTON

Personal Author(s):

• Patterson,John M.

Report Date:

1969-09-01

Pagination or Media Count:

10.0

Abstract:

Research was undertaken to elucidate product formation and the reaction path followed in the thermally-induced isomerization of N-substituted pyrroles. Various parameters such as the effect of substituents pyrrole-ring substituents and migrating-group substituents on migration aptitudes, on product distribution and on reaction rate were investigated. The study of a reaction in which the potential migrating group is optically active was proposed in order to determine the nature of migration process. Author

Descriptors:

• (*PYRROLES
• *MOLECULAR ISOMERISM)
• STEREOCHEMISTRY
• REACTION KINETICS
• PYROLYSIS

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE