Accession Number:

AD0697089

Title:

CHEMISTRY OF STRAINED OLEFINS.

Descriptive Note:

Final rept. 1 Oct 65-30 Sep 69,

Corporate Author:

WISCONSIN UNIV MADISON DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1969-06-01

Pagination or Media Count:

9.0

Abstract:

Final report on studies concerned with the experimental tests of theory in bond breaking reactions of strained ring compounds. The first test of orbital symmetry control of a thermal 1,3-sigmatropic rearrangement was established. Preliminary work was carried out on the construction of a test in the 1,5-sigmatropic case. New synthetic approaches have been developed to the optically active cycloheptatrienes needed for stereochemical experiments. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE