Accession Number:

AD0697039

Title:

PREPARATION, REACTIONS AND STRUCTURES OF TRANSITION METAL OLEFIN COMPOUNDS AND RELATED SUBSTANCES.

Descriptive Note:

Final rept. 1 Jan 65-1 Jul 69,

Corporate Author:

IOWA UNIV IOWA CITY DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1969-10-21

Pagination or Media Count:

13.0

Abstract:

A summary of work performed during the four year grant period is outlined. Major areas involved in the acquisition of new knowledge were 1 The structures of metal-olefin compounds containing silver, palladium and iron 2 New olefin complexes of silver and copper 3 New manganese and rhenium carbonyl complexes containing nitriles and aromatic ligands. 4 A systematic examination of the n.m.r. spectra of platinum and palladium olefin compounds 5 A kinetic study on the solvolysis of platinum and palladium compounds. 6 New complexes of triphenylphosphine gold compounds involving a periodic valence states of gold 7 A study of the thermal motion of CS2 in the solid state and its relation to the motion of the olefin group in metal-olefins. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE