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THE OXIDATION OF ARSENIC (III) AND ANTIMONY (III).
Final rept. 1 Feb 63-30 Sep 67
VIRGINIA POLYTECHNIC INST AND STATE UNIV BLACKSBURG DEPT OF CHEMISTRY
Pagination or Media Count:
The kinetics of the CrVI-AsIII reaction have been investigated in H2PO4--HPO4 buffers. Complex kinetics have been obtained. The rate law found is first order in total CrVI and AsIII with a complex dependence upon buffer composition. The data point to the reaction proceeding via two activated complexes, H2PO4- . HCrO4- . AsIII and HPO4- . HCrO4- . AsIII.
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