Accession Number:

AD0692336

Title:

THE NUCLEAR MAGNETIC RESONANCE SPECTRA OF PYRROLE AND (N-D)PYRROLE,

Descriptive Note:

Corporate Author:

DEFENCE STANDARDS LABS MARIBYRNONG (AUSTRALIA)

Personal Author(s):

Report Date:

1969-02-26

Pagination or Media Count:

8.0

Abstract:

The proton magnetic resonance spectrum at 60 MHz of pyrrole, spin-decoupled from 14N, has been studied under high resolution. Similar studies have been made on N-Dpyrrole in which the proton spectrum was obtained simultaneously spin-decoupled from both the 14N and 2H nuclei. Analysis of the 13C-H spectra of pyrrole and N-Dpyrrole, observed in natural abundance, gave values for all six proton-proton spin-spin couplings. Values for some of the couplings have been obtained directly and unambiguously from the spectra of samples of N-Hpyrrole and N-Dpyrrole in which the C-H protons have been predominantly exchanged for deuterium. Author

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE