Accession Number:

AD0692213

Title:

THE IONS (CH3S)(+), (C2H5S)(+) AND (CH3O)(+) FORMED BY ELECTRON-IMPACT,

Descriptive Note:

Corporate Author:

DEFENCE STANDARDS LABS MARIBYRNONG (AUSTRALIA)

Report Date:

1968-10-28

Pagination or Media Count:

7.0

Abstract:

The mass spectra of deuterated species shows that both the isomeric ions CH2SH and CH3-S are formed in the ratio 21 from CH3SH the ions CH3CHSH and CH3CH2S in the ratio 0.81 from CH3CH2SH and CH2OH and CH3-O in the ratio 6.71 from methanol. The heats of formation of CH3S and C2H5S are of the order of 222 and 203 Kcalmole respectively. The isomeric ions cannot be distinguished on thermodynamic grounds. Author

Subject Categories:

  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE