Accession Number:

AD0691289

Title:

COMPLEXES OF B9H10CHP(-) AND B9H10CHAs(-) WITH GROUP VI METAL CARBONYLS.

Descriptive Note:

Technical rept.,

Corporate Author:

INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY

Personal Author(s):

• Todd,Lee J.
• Silverstein,Howard T.
• Beer,Don C.

Report Date:

1969-07-01

Pagination or Media Count:

27.0

Abstract:

The photochemical reaction of CH34NB9H10CHE E P or As with group VI metal carbonyls lead to the formation of complexes of the general formula, CH34NB9H10CHEMCO5. Available evidence suggests that the phosphorus or arsenic atom of the ligand is sigma bonded to the metal carbonyl in these new derivatives. Author

Descriptors:

• *METAL CARBONYLS
• *PHOSPHORUS COMPOUNDS
• *ORGANOMETALLIC COMPOUNDS
• *ARSENIC COMPOUNDS
• BORANES
• BORANES
• BORANES
• SYNTHESIS(CHEMISTRY)
• NUCLEAR MAGNETIC RESONANCE
• IONS
• IRON COMPOUNDS
• CHEMICAL BONDS
• COMPLEX COMPOUNDS
• CHROMIUM COMPOUNDS
• MOLYBDENUM COMPOUNDS
• TUNGSTEN COMPOUNDS
• PHOTOCHEMICAL REACTIONS

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE