THERMOANALYTICAL INVESTIGATIONS OF THE CUPRATE (III) ANION.
NAVAL ORDNANCE LAB WHITE OAK MD
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Thermogravimetric and differential thermal analysis of new reactions yielding copperIII compounds are discussed. Potassium metal plus copperII oxide yields potassium cuprateIII at ca 280C. Sodium and barium peroxide plus copperII oxide yield sodium and barium cuprate III respectively at ca 700C. The reaction parameters involved in these reactions are identified and discussed. CopperII oxide was observed to disproportionate in the presence of barium oxide at temperatures greater than 650C yielding copperI oxide and barium cuprateIII. Author
- Inorganic Chemistry
- Physical Chemistry