Accession Number:

AD0686429

Title:

REACTION OF THE CHLORINE-FLUORINE INTERHALOGENS WITH HYDROGEN.

Descriptive Note:

Phase rept. Sep 68-Jan 69,

Corporate Author:

AIR FORCE ROCKET PROPULSION LAB EDWARDS AFB CALIF

Personal Author(s):

Report Date:

1969-04-01

Pagination or Media Count:

21.0

Abstract:

The reactions of ClF5, ClF3, and ClF with an excess of H2 were studied over the temperature range 351 to 525K in a gas-phase-flow reactor. The activation energy for each reaction is in each case approximately one half the interhalogen dissociation activation energy. The relationship between reactive stream separation and similar gas-phase reaction is shown. Calculated values are reported respectively for the H ClF5, ClF3, and ClF exchange rate constants. Author

Subject Categories:

  • Physical Chemistry
  • Crystallography

Distribution Statement:

APPROVED FOR PUBLIC RELEASE