Accession Number:

AD0680814

Title:

ORGANOMETALLIC CHEMISTRY.

Descriptive Note:

Final scientific rept. 1 Sep 65-30 Sep 68,

Corporate Author:

BRISTOL UNIV (ENGLAND) DEPT OF INORGANIC CHEMISTRY

Personal Author(s):

• Stone,F. G. A.

Report Date:

1968-10-15

Pagination or Media Count:

21.0

Abstract:

This report summarises studies in three main areas 1 Fluorocarbon complexes of transition metals 2 metal carbonyl complexes of the transition metals of the 4d and 5d series 3 organoderivatives of silicon and tin. A summary and a bibliography of the 25 publications produced during the investigation forms the body of the Report. Among the main discoveries were new synthesis of rhodium and iridium carbonyls formation of fluorocarbon-metal complexes by oxidative-addition of d8 or d10 complexes, and the formation of new siloxanes from reactions between perfluoroketones and silthianes. Author

Descriptors:

• *ORGANOMETALLIC COMPOUNDS
• *FLUORINE COMPOUNDS
• *METAL CARBONYLS
• TRANSITION METALS
• SILICON COMPOUNDS
• TIN COMPOUNDS
• COMPLEX COMPOUNDS
• SYNTHESIS(CHEMISTRY)
• RHODIUM COMPOUNDS
• IRIDIUM COMPOUNDS
• SILOXANES
• DIENES
• UNITED KINGDOM

Subject Categories:

• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE