Accession Number:

AD0680676

Title:

REACTIONS OF OZONIDES. VII. ISOLATION AND OXIDATION OF OZONOLYSIS PRODUCTS FROM 1-DECENE,

Descriptive Note:

Corporate Author:

ROYAL MILITARY COLL OF CANADA KINGSTON (ONTARIO) DEPT OF CHEMISTRY AND CHEMICAL ENGINEERING

Personal Author(s):

Report Date:

1968-04-26

Pagination or Media Count:

5.0

Abstract:

1-Decene ozonide 1 was isolated by column chromatography of the mixed products of ozonation of 1-decene 2 in several nonpolar solvents. 1-Methoxy- 3 and 1-tertiary butoxynonane-1-hydroperoxide 4 were similarly obtained. The thin-layer chromatographic separation of these products from each other and from other ozonation products was examined. Compounds 3 and 4 were smoothly oxidized to di-1-alkoxyalkylperoxides by CeIV. The stoichiometry of this reaction, examined by isothermal calorimetry, was 11. Compounds 1, 3, and 4 were oxidized by CF3CO3H and by other oxidizing agents to nonanoic acid with chain degradation loss of 2-30. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE