NOVEL SIGMA-BONDED TRANSITION METAL CARBORANE COMPLEXES.
CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY
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Reactions of 1,2-B10C2H11- and 1,10-B8C2H8-2 ions with Pi-C5H5FeCO22 in ether solvents produces sigma-bonded iron carborane complexes. The two complexes reported are 1-pi-C5H5FeCO2-2-CH3-sigma-1,2-B10C2H10 and 1,10-pi-C5H5FeCO22 - 1,10-sigma-B8C2H8 which were prepared in 47 and 71 yield, respectively. Author
- Inorganic Chemistry