Accession Number:

AD0679765

Title:

NOVEL SIGMA-BONDED TRANSITION METAL CARBORANE COMPLEXES.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY

Personal Author(s):

• Smart,James C.
• Garrett,Philip M.
• Hawthorne,M. Frederick

Report Date:

1968-11-25

Pagination or Media Count:

9.0

Abstract:

Reactions of 1,2-B10C2H11- and 1,10-B8C2H8-2 ions with Pi-C5H5FeCO22 in ether solvents produces sigma-bonded iron carborane complexes. The two complexes reported are 1-pi-C5H5FeCO2-2-CH3-sigma-1,2-B10C2H10 and 1,10-pi-C5H5FeCO22 - 1,10-sigma-B8C2H8 which were prepared in 47 and 71 yield, respectively. Author

Descriptors:

• (*ORGANOBORANES
• *METAL CARBONYLS)
• (*COMPLEX COMPOUNDS
• ORGANOBORANES)
• IRON COMPOUNDS
• SYNTHESIS(CHEMISTRY)
• IONS

Subject Categories:

• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE