SYNTHESIS OF NOVEL SUBSTITUTED (3)-1,7-DICARBAUNDECABORATE(12) IONS FROM 1,8-DICARBACLOSOUNDECABORANE(11) AND CARBANIONS.
CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY
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The reaction of the B9C2H11 carborane and its C-substituted derivatives with carbanions, derived from a series of closo-carboranes by C-H ionization, react to form anions in which the two carborane systems are mutually bonded. The product anions are considered to be B-substituted derivatives of the 3-1, 7-B9C2H12- ion. Author
- Inorganic Chemistry