Accession Number:

AD0673502

Title:

METALS IN NON-METALLIC SOLVENTS.

Descriptive Note:

Final rept.,

Corporate Author:

LEICESTER UNIV (ENGLAND) DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1968-01-31

Pagination or Media Count:

41.0

Abstract:

The electron spin resonance absorption of the solvated sodium atom in ammonia-ethylamine mixtures is reported. The atomic characters of the other solvated alkali atoms are compared with that of sodium. The dependence of line-width upon alkali metal nuclear spin configuration is interpreted in terms of an equilibrium between two species, one having a very small hyperfine coupling and the other having a coupling close to the atomic value. Concentration-broadening of the central singlet is interpreted in terms of interactions with the diamagnetic species which account for the majority of the dissolved metal. Author

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE