METALS IN NON-METALLIC SOLVENTS.
LEICESTER UNIV (ENGLAND) DEPT OF CHEMISTRY
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The electron spin resonance absorption of the solvated sodium atom in ammonia-ethylamine mixtures is reported. The atomic characters of the other solvated alkali atoms are compared with that of sodium. The dependence of line-width upon alkali metal nuclear spin configuration is interpreted in terms of an equilibrium between two species, one having a very small hyperfine coupling and the other having a coupling close to the atomic value. Concentration-broadening of the central singlet is interpreted in terms of interactions with the diamagnetic species which account for the majority of the dissolved metal. Author
- Physical Chemistry