SYNTHESIS AND PROPERTIES OF ALKAROMATIC CHLOROCARBONS.
Final scientific rept. 1 Nov 63-31 Dec 67,
CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS BARCELONA (SPAIN) DEPARTAMENTO DE QUIMICA ORGANICA
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The study of the alkaromatic chlorocarbons initiated some years ago was continued. New syntheses of highly strained, overcrowded chlorocarbons were performed. In total, fifteen new reactions were found. A new class of substances was discovered the Inert Free Radicals. Also, stable alpha-chlorocarbanion salts and other chlorinated carbanions were prepared for the first time. A total of seventy-three new highly chlorinated and perchlorinated substances is reported, including twelve carbon free radicals. Author
- Organic Chemistry