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A CHEMICAL KINETIC STUDY OF SUBSTITUTION REACTION IN COORDINATION COMPOUNDS INVOLVING TRANSITION-METAL IONS HAVING THE D8 ELECTRONIC CONFIGURATION.
Final rept. 1 Nov 65-30 Jun 68,
NEVADA UNIV RENO DEPT OF CHEMISTRY
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Detailed studies were completed of the kinetics and mechanisms of the acid hydrolyses of the NiII and PdII complexes with ethylenebisbiguanide. The stability constant for the NiII complex with ethylenebisbiguanidde was determined. Employing a computer program developed from evaluating the ionization constants of ethylene bisbiguanidinium ion, the two acid dissociation constants of squaric acid were redetermined. Author
APPROVED FOR PUBLIC RELEASE