Accession Number:

AD0669167

Title:

THE FORMS OF THE EQUATIONS OF THE SELF-CONSISTENT FIELD (O VIDAKH URAVNENII SAMOSOGLASOVANNOGO POLYA),

Descriptive Note:

Corporate Author:

AMERICAN METEOROLOGICAL SOCIETY BOSTON MASS

Personal Author(s):

Report Date:

1965-04-01

Pagination or Media Count:

10.0

Abstract:

It is pointed out that neglect of the exchange terms between shells in the Fock equations leads to equations that differ substantially from the Hartree equations in the general case. However, the use of an atomic wave function in the form of a single product of orbitals is ambiguous. It is shown that the Hartree equations can be obtained unambiguously by the use of an atomic function in the form of a product of radial orbitals. The atomic wave function expressed as a single determinant in the unrestricted Hartree-Fock method is pointed out to be ambiguous. Author

Subject Categories:

  • Atomic and Molecular Physics and Spectroscopy
  • Quantum Theory and Relativity

Distribution Statement:

APPROVED FOR PUBLIC RELEASE