PENTAFLUOROSULFUR CARBONYL FLUORIDE, PENTAFLUOROSULFUR FLUOROFORMATE AND PENTAFLUOROSULFUR PEROXOFLUOROFORMATE
WASHINGTON UNIV SEATTLE SEATTLE
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The compounds SF5CFO, SF5OCFO and SF5OOCFO were produced in low yields by ultraviolet irradiation of the following mixtures, respectively 1 S2F10 and C2O2F2 2 SF5OF and C2O2F2 3 SF5OOSF5, and C2O4F2. Each of the new compounds reacts readily with a solution of sodium hydroxide, and has infrared and 19F NMR spectra in keeping with its structure.