DEUTERIUM ISOTOPE STUDIES ON 2,3-DICARBAHEXABORANE(8).
CALIFORNIA STATE COLL LOS ANGELES DEPT OF CHEMISTRY
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Deuterium exchange at various positions on the C2B4H8 molecule was studied. D2 exchanges with all boron-bonded hydrogen atoms, and B2D6 in the presence of diglyme exchanges only at the 4-, 6-terminal positions. The CH32C2B4H6-DCl exchange, catalyzed by aluminum chloride, occurs at both apex and base terminal positions. C,C-Dideuterio-2,3-dicarbahexaborane8, D2C2B4H6, was prepared for comparison of the infrared spectrum. Author
- Inorganic Chemistry