Accession Number:

AD0655807

Title:

ALUMINIUM-NITROGEN AND ALUMINIUM-PHOSPHORUS POLYMERS

Descriptive Note:

Final rept. 1 Oct 1964-30 Sep 1966

Corporate Author:

SUSSEX UNIV BRIGHTON (UNITED KINGDOM) CHEMICAL LAB

Report Date:

1967-06-01

Pagination or Media Count:

29.0

Abstract:

The products of the reaction between methylamine and trialkylaluminiums were studied by molecular weight determinations as well as by infrared and nuclear magnetic resonance spectroscopy. Stereoisomers of R2A1NHR3 are indicated. The reactions of phosphine adducts of organoaluminium compounds were studied and an order of base strength with respect to triethylaluminium was established by displacement reactions. Polymers of composition RA1PRx were prepared but crystalline products were obtained. Aluminium-nitrogen seem to be more stable than corresponding aluminium- phosphorus frameworks.

Subject Categories:

  • Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE