Accession Number:

AD0654328

Title:

TERTIARY PHOSPHINE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II).

Descriptive Note:

Doctoral thesis,

Corporate Author:

MARYLAND UNIV COLLEGE PARK DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1967-06-01

Pagination or Media Count:

121.0

Abstract:

The results are reported of research which was undertaken 1 to determine the chemical shifts of cis and trans isomers of platinumII complexes in hope of gaining information about pi-bonding in the Pt-P bond, and to extend this study to palladiumII 2 to determine trends which may exist within a series of ligands for the purpose of developing expressions that would enable calculation of chemical shifts for complexes 3 to expand the knowledge of the chemistry of tertiary phosphine complexes of platinumII and palladiumII and 4 to determine phosphorus-phosphorus coupling constants by preparing a complex of a chelating diphosphine R2PCH2CH2PR2 or by preparing a complex containing two different phosphines.

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE