TERTIARY PHOSPHINE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II).
MARYLAND UNIV COLLEGE PARK DEPT OF CHEMISTRY
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The results are reported of research which was undertaken 1 to determine the chemical shifts of cis and trans isomers of platinumII complexes in hope of gaining information about pi-bonding in the Pt-P bond, and to extend this study to palladiumII 2 to determine trends which may exist within a series of ligands for the purpose of developing expressions that would enable calculation of chemical shifts for complexes 3 to expand the knowledge of the chemistry of tertiary phosphine complexes of platinumII and palladiumII and 4 to determine phosphorus-phosphorus coupling constants by preparing a complex of a chelating diphosphine R2PCH2CH2PR2 or by preparing a complex containing two different phosphines.
- Inorganic Chemistry