Accession Number:

AD0647810

Title:

1,2-BIS(SUBSTITUTED)-O-CARBORANE COMPLEXES. II. NICKEL(II) AND COBALT(II) COMPLEXES DERIVED FROM THE LIGAND 1,2-BIS(MERCAPTO)-O-CARBORANE.

Descriptive Note:

Technical rept.,

Corporate Author:

OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS GROUP

Personal Author(s):

• Smith,H. D. , Jr.
• Robinson,Martin A.
• Papetti,S.

Report Date:

1967-02-01

Pagination or Media Count:

21.0

Abstract:

Some nickelII and cobaltII salts have been found to react readily with 1,2-bismercapto-o-carborane in the presence of stabilizing phosphorous ligands or the tetraethylammonium cation to yield square planar MS2P2 and MS42 complexes. Electronic spectra of the nickel complexes are discussed. Author

Descriptors:

• (*ORGANOBORANES
• *COMPLEX COMPOUNDS)
• (*NICKEL COMPOUNDS
• COMPLEX COMPOUNDS)
• (*COBALT COMPOUNDS
• COMPLEX COMPOUNDS)
• SYNTHESIS
• SALTS
• SPECTROSCOPY

Subject Categories:

• Organic Chemistry
• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE