BASIC RESEARCH ON SYNTHESIS OF NEW PHOSPHORUS-NITROGEN REAGENTS.
Interim rept. 15 Nov 64-15 Nov 65,
MONSANTO RESEARCH CORP DAYTON OHIO
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Two compounds of the general formula RO2P-ONHP-OOR2 were prepared and applied in the preparation of metal derivatives. Tetraethyl imidodiphosphate and tetraphenyl imidodiphosphate were prepared by published methods. New crystalline derivatives were obtained for the first compound with zinc, for the second compound with zinc, palladium, lanthanum, cerium, praseodymium and europium. A tetramminepalladium II derivative of tetraphenyl imidodiphosphate is promising for the gravimetric determination of palladium. Author
- Inorganic Chemistry
- Organic Chemistry