TRANSITION METAL COMPLEXES WITH TWO NEW SERIES OF TETRADENTATE LIGANDS.
Final rept., 1 Oct 63-30 Sep 66,
OHIO STATE UNIV RESEARCH FOUNDATION COLUMBUS
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An investigation was undertaken of the coordinating properties of flexible tetradentate phosphorus, arsenic, and nitrogen ligands of the type DCH2CH2CH2D3, where D does not D. A series of nickel II complexes with the five coordinate NiligandX cations was isolated and studied extensively. A number of PdII and CoII complexes were also examined. A second series of studies involved the nature of bonding in boron-transition metal complexes having groups of the type BOCH2CH2NR2. Also, the synthesis of a number of tetradentate compounds with boron-carbon bonds was undertaken e.g., BPh-AsO23.
- Inorganic Chemistry