Accession Number:

AD0646013

Title:

TRANSITION METAL COMPLEXES WITH TWO NEW SERIES OF TETRADENTATE LIGANDS.

Descriptive Note:

Final rept., 1 Oct 63-30 Sep 66,

Corporate Author:

OHIO STATE UNIV RESEARCH FOUNDATION COLUMBUS

Personal Author(s):

Report Date:

1966-11-14

Pagination or Media Count:

11.0

Abstract:

An investigation was undertaken of the coordinating properties of flexible tetradentate phosphorus, arsenic, and nitrogen ligands of the type DCH2CH2CH2D3, where D does not D. A series of nickel II complexes with the five coordinate NiligandX cations was isolated and studied extensively. A number of PdII and CoII complexes were also examined. A second series of studies involved the nature of bonding in boron-transition metal complexes having groups of the type BOCH2CH2NR2. Also, the synthesis of a number of tetradentate compounds with boron-carbon bonds was undertaken e.g., BPh-AsO23.

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE