Accession Number:

AD0645778

Title:

THE MICROWAVE SPECTRUM, STRUCTURE, DIPOLE MOMENT AND QUADRUPOLE COUPLING CONSTANT OF GERMYL CYANIDE,

Descriptive Note:

Corporate Author:

HARVARD UNIV CAMBRIDGE MASS DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1966-06-30

Pagination or Media Count:

16.0

Abstract:

The symmetric top spectra of ten isotopic species of GeH3CN were observed and measured. From the rotational constants obtained the following structural parameters were derived rC-N 1.55 plus or minus 0.001 A and rGe-C 1.919 plus or minus 0.001 A, assuming rGe-H 1.529 A and a tetrahedral distribution about the Ge atom. From an analysis of the splittings observed in the 1 to 2 transitions of GeH3CN a quadrupole coupling constant for the nitrogen nucleus of -5.0 plus or minus 0.1 Mcs was obtained. Analysis of the Stark effect gives a dipole moment of 3.99 plus or minus 0.05 D. Author

Subject Categories:

  • Inorganic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE