A RADIOCHEMICAL TECHNIQUE TO STUDY THE SOLVENT TRANSFER REACTION IN THE POLYMERISATION OF TETRAHYDROFURAN BY PHOSPHORUS PENTAFLUORIDE.
EXPLOSIVES RESEARCH AND DEVELOPMENT ESTABLISHMENT WALTHAM ABBEY (ENGLAND)
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A radiochemical technique using 14C-labelled diethyl ether was used to prove that a chain transfer reaction to solvent occurs during the polymerisation of tetrahydrofuran by phosphorus pentafluoride. A mechanism to describe the chain transfer reaction was suggested. Author
- Organic Chemistry
- Radiation and Nuclear Chemistry