SMALL RING COMPOUNDS.
Final rept. 1 Oct 61-30 Sep 65,
FORDHAM UNIV BRONX N Y DEPT OF CHEMISTRY
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A summary is given of research, the ultimate objective of which was the synthesis of small ring compounds fused to an aromatic frame, such that the aza-atom was either exocyclic or endocyclic to the small ring. Topics include Ring expansion of 1-indanones to cyclic hydroxamic acids Oxindolylene chemistry Reactions of 2, 3-disubstituted quinoxalines Origin of the carbonyl doublet in 2-indanone and trans-hexahydro-2-indanone Syntheses of cis- and trans-7-azabicyclo4.2.0octanes Preparation of beta-lactams containing an exocyclic double bond Synthesis and reactions of cyclic amidines.
- Organic Chemistry