Accession Number:

AD0640565

Title:

TRANSITION-METAL FLUOROCARBON COMPLEXES. PART I. DERIVATIVES OF PERFLUORO-OLEFINS.

Descriptive Note:

Final technical rept.,

Corporate Author:

IMPERIAL COLL OF SCIENCE AND TECHNOLOGY LONDON (ENGLAND)

Report Date:

1961-01-01

Pagination or Media Count:

23.0

Abstract:

The interaction of tri-iron dodecacarbonyl, Fe3 CO12, with octafluorocyclohexa-1,3- or 1,4-dienes forms a compound C6F8FeCO3 which must be formulated as a pi-bonded olefin complex. In contrast, the interaction of tetrafluoroethylene with Fe3CO12 gives a compound C4F8FeCO4 in which the iron atom is bound to carbon by sigma-bonds in a perfluorocycloalkane ring. Infrared, high-resolution nuclear magnetic resonance and mass spectroscopic studies support these formulations. Products from the interaction of C2F4 with Co2CO8 and pi-C5H52Co and of the latter with CF3I are described. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE