STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. VII. SYNTHESIS OF SOME HETERO-POLYMERS CONTAINING GERMANIUM, TIN, AND LEAD IN THE MAIN POLYMER CHAIN.
INSTITUTE FOR ORGANIC CHEMISTRY TNO UTRECHT (NETHERLANDS)
Pagination or Media Count:
It was shown that di-p-styrenyl derivatives of germanium, tin, and lead as well as 1,4-divinylbenzene and 3,9-divinylspirobi meta-dioxane react with diphenyltin dihydride to yield linear poly-addition polymers containing tin or tin and germanium or lead in the main polymer chain. The polmeric products were characterized by infrared spectroscopy, analytical data and molecular weights, the latter varying from 14.000 for the lead-containing polymer to 110.000 for the 1,4-divinylbenzene adduct. Reactions of triphenyltin hydride and diphenyltin dihydride with mono- and di-p-styrenyl derivatives of germanium, tin, and lead yielding monomeric compounds containing two and three hydrocarbon-linked metal atoms were carried out as well. Author
- Polymer Chemistry