TRIPHENYLSILOXY DERIVATIVES OF BIS-CYCLOPENTADIENYL TITANIUM.
INSTITUTE FOR ORGANIC CHEMISTRY TNO UTRECHT (NETHERLANDS)
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Contrary to a report in the literature one or two chlorine atoms in bis-cyclopentadienyl titanium dichloride may be replaced by triphenylsiloxy groups with retention of the cyclopentadienyl groups. Orange-colored triphenyl-siloxy-bis-cyclopentadienyl titanium chloride m.p. 210-212C and yellow-colored bis-triphenylsiloxy-bis-cyclopentadienyl titanium m.p. 208-210C were isolated in good yield. Author
- Organic Chemistry