Accession Number:

AD0640547

Title:

STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. XVI. SYNTHESIS OF ORGANOGERMANIUM COMPOUNDS CONTAINING THE P-PHENYLENE GROUP. SOME INFRARED CHARACTERISTICS OF P-PHENYLENE DERIVATIVES OF SILICON, GERMANIUM, TIN AND LEAD.

Descriptive Note:

Technical note,

Corporate Author:

INSTITUTE FOR ORGANIC CHEMISTRY TNO UTRECHT (NETHERLANDS)

Report Date:

1964-03-20

Pagination or Media Count:

21.0

Abstract:

A few oligomeric and polymeric p-phenylenegermanes have been prepared by Wurtz-type condensation reactions from p-chlorophenyl and chloro-germanes. The oligomerio and polymeric products obtained have been characterized by infrared spectroscopy, elementary analysis and molecular weight determinations. Infrared spectra in the rocksalt region of phenyl and p-phenylene derivatives of silicon, germanium, tin and lead are discussed. The spectra of the p-phenylene compounds show some characteristic absorption bands shifting to lower frequencies as the weight of the metal atoms in the molecule increases. Author

Subject Categories:

  • Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE