RESEARCH ON SULFUR-PHOSPHORUS-NITROGEN POLYMERS; ON SULFUR-NITROGEN-SILICON-COMPOUNDS.
Technical scientific note,
HEIDELBERG UNIV (WEST GERMANY) DEPT OF INORGANIC CHEMISTRY (1ST)
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The bonds between Si and N in hexamethyldisilazan and trimethyl-N-methyl-aminosilane readily undergo heterolytic fission. Using one such reaction, various derivatives were prepared in which one or two Si atoms are bonded with sulphuryl groups, SO2, through HN bridges or through a CH3N bridge, or, resp. through a CH33Si-N bridge. When two HN bridges are present, one may be replaced by O. Author
- Polymer Chemistry