Accession Number:

AD0639929

Title:

RESEARCH ON PHOSPHORUS-NITROGEN-SILICON COMPOUNDS.

Descriptive Note:

Technical scientific note,

Corporate Author:

HEIDELBERG UNIV (WEST GERMANY) DEPT OF INORGANIC CHEMISTRY (1ST)

Personal Author(s):

Report Date:

1959-11-15

Pagination or Media Count:

14.0

Abstract:

The reactions of hexamethyldisilazane and trimethyl-N-methyl-aminosilane with amides and hydrazides of esters of phosphoric acid result in heterolysis of Si-N-compounds and trimethylsilyl-amides or -hydrazides of the corresponding phosphoric acid are formed. Monochlorides of esters of phospheric acid also react with hexamethyldisilazane under heterocyclic fission of the Si-N-compound, while the reaction of trimethyl-N-methylamino-silane results in the substitution of the H-atom attached to the N-atom without any fission of the Si-N-compound. Derivates of the dichlorophospheric acid are obtained from silazane and OPC13. Author

Subject Categories:

  • Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE