SOME TERTIARY ALCOHOLS DERIVED FROM M-CARBORANE.
OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS DIV
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A report is given of the preparation of several tertiary diols of m-carborane, such as B10H10C2CH32OH2 and their fluorinated derivatives such as B10H10C2CCF32OH2. These were prepared by reaction of the dilithio salt of m-carborane with the appropriate ketone. The following compounds were prepared - M-carboranyl-1,7-bis dimethylcarbinol m-carboranyl-1,7-bismethyl trifluoro-methyl carbinol m-carboranyl-1,7-bis di-trifluoromethyl carbonol m-carboranyl-1,7-bischloro difluoromethyl trifluoromethyl carbinol.
- Organic Chemistry