Accession Number:

AD0639498

Title:

SOME TERTIARY ALCOHOLS DERIVED FROM M-CARBORANE.

Descriptive Note:

Technical rept.

Corporate Author:

OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS DIV

Personal Author(s):

Report Date:

1966-09-01

Pagination or Media Count:

8.0

Abstract:

A report is given of the preparation of several tertiary diols of m-carborane, such as B10H10C2CH32OH2 and their fluorinated derivatives such as B10H10C2CCF32OH2. These were prepared by reaction of the dilithio salt of m-carborane with the appropriate ketone. The following compounds were prepared - M-carboranyl-1,7-bis dimethylcarbinol m-carboranyl-1,7-bismethyl trifluoro-methyl carbinol m-carboranyl-1,7-bis di-trifluoromethyl carbonol m-carboranyl-1,7-bischloro difluoromethyl trifluoromethyl carbinol.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE