EMPIRICAL CALCULATION OF THE DISSOCIATION ENERGIES OF BORON-CONTAINING BONDS.
FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO
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Paulings empirical equation is suitable in the calculation of energies of boron-containing bonds. The discrepancy between the calculated and experimental values of B-NMe2 is relatively large. This could be due to the fact that the double bond character of the compound is not taken into consideration. From the energy and from the ionic character, it is possible to determine the relative stability of the various boron bonds. Author
- Physical Chemistry