PHYSICAL AND PREPARATIVE STUDIES OF MOLYBDENUM AND TUNGSTEN COMPLEXES.
Scientific interim rept., Dec 64-Nov 65,
TULANE UNIV NEW ORLEANS LA
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Several new molybdenum complexes containing chelated 8-hydroxy-quinolinato ligands, including MoClC5H5N C9H6NO2 and MoCl2C5H5N2C9H6NO and three oxomolybdenumV derivatives were prepared and studied. A cationic molybdenumIII species containing chelated ethylenediamine and a cationic tungstenIV species containing chelated 2,21-bipyridine were also synthesized. Other preparative studies included photochemical investigations with tungstenIV. The complex formerly designated as K2MoCl5H2O by other workers was shown to have less than enough potassium for such a formula, the spectra of K3MoCl6 as currently in the literature has been shown to be incorrect, and the apparent discrepancy in the literature concerning the tetrazole complex FeC2F3N42.2H2O was explained. Author
- Inorganic Chemistry