Accession Number:

AD0631366

Title:

PHOTOCHEMISTRY OF 2-ALKYLAMINOPHENOXAZ -3-ONES. II.

Descriptive Note:

Technical rept.,

Corporate Author:

RESEARCH TRIANGLE INST DURHAM N C

Personal Author(s):

Report Date:

1966-01-01

Pagination or Media Count:

19.0

Abstract:

The photochemistry of 2-dialkylaminophenoxaz-3-ones was investigated. In general these compounds were found to be more photo-reactive than the corresponding monoalkylaminophenoxaz-3-ones. The 2-dimethylaminophenoxaz-3-one underwent photochemical demethylation. Irradiation of the 2-polymethyleneiminophenoxaz-3-ones gave different products depending upon the size of the polymethyleneimine ring. Propyl-, pentyl-, and hexyl-methyleneimine phenoxazones gave novel pentacyclic dicarbomethoxy dimethyl alkyleneoxazolino phenoxazines. Stable dihydrophenoxaz-3-ones were obtained by the reduction of butyl-, pentyl-, and hexyl-methyleneimine phenoxazones.

Subject Categories:

  • Organic Chemistry
  • Radiation and Nuclear Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE