Accession Number:

AD0627812

Title:

COMPLEX HYDRIDES AND ZEROVALENT DERIVATIVES OF TRANSITION METALS.

Descriptive Note:

Final rept.,

Corporate Author:

MILAN UNIV (ITALY) ISTITUTO DI CHIMICA GENERALE

Personal Author(s):

Report Date:

1965-11-01

Pagination or Media Count:

49.0

Abstract:

The following papers are included in whole or in summary Hydridocomplexes of transition metals description of compounds of the type MeHDPE2 Me Co, Rh DPE C2H2 P C6H532 and of CoH2DPE2ClO4 Basic behaviour of platinum O derivatives the reaction PtL3 HCl PtHL3Cl and PtHL3Cl PtHL2ClLL C6H53P are described and discussed Tricarbonyl-and hydridotricarbonyl-bistriphenylphosphinerhenium the reaction ReH5L3 CO ReHCO3L22H2ll - p9c6H53 and ReHCO3L2 to ReCO3L2 monomeric paramagnetic are described Novel rhenium triphenylphosphine compounds description of the preparation and properties of the new hydrides ReH5L2 and ReH5L3L PC6H53 Triphenylphosphine gold O gold I compounds the preparation and properties of the compounds Au5L4 X L PC6H53, X Cl, NO3, ClO4, BC6H54, SnCl3 and Au3L2 X X I, CN, SnI3 are described and discussed New triphenylphosphine iridium compounds description of an insaturated hydride IrH3L2 L PC6H53, of the carbonylhydrides IrH3COL2 and IrHCOL2, of a cationic carbonylderivative IrCO3L2ClO4 and of a metallorganic compound IrCO2MeCO2L2.

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE