Accession Number:

AD0627278

Title:

USE OF EPR (ELECTRON PARAMAGNETIC RESONANCE) FOR THE STUDY OF ACTIVE CENTERS IN LIQUID PHASE OXIDATION REACTIONS,

Descriptive Note:

Corporate Author:

FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Report Date:

1966-01-03

Pagination or Media Count:

12.0

Abstract:

By the method of electron paramagnetic resonance cumene peroxide radicals were detected in the reaction of cumene oxidation, catalyzed by cobalt stearate or initiated azobisisobutyronnitrile and dicyclohexlpercarbonate. Stationary concentrations of radicals were measured at various initiation rates in conditions of going oxidation reaction. The concentration of peroxide radicals, calculated by known values of rates of initiation and by the value of recombination velocity constant, are measured. Author

Subject Categories:

  • Organic Chemistry
  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE