A KINETIC STUDY OF THE THERMAL DECOMPOSITION OF SELECTED CYCLOHEXYL AND PHENYLSILANES.
Research rept. 1 May 64-30 Apr 65,
BATTELLE MEMORIAL INST COLUMBUS OHIO
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The decomposition kinetics of the phenylhydrosilanes mono-, di-, and triphenylsilane were studied with the aid of flow techniques. Decomposition occurs via second-order disproportionation reactions. Based on the kinetic factors of entropy and energy of activation and pre-exponentional factor, it is concluded that the decomposition occurs via a four-centered activated complex. Author
- Organic Chemistry
- Physical Chemistry